Розрахунок сольового індексу Рідких Комплексних Добрив. Calculating Salt Index. Dr. John J. Mortvedt

Розрахунок сольового індексу

Вміст солі – одна з найважливіших характеристик добрив, що використовуються для висадки насіння в рядок. СІ – це міра концентрації солі, яку в ґрунтовому розчині викликає добриво.

СІ матеріалу виражається як відношення збільшення осмотичного тиску розчину солі, що виробляється конкретним добривом, до осмотичного тиску тієї ж ваги NaNO3, що ґрунтується на відносному значенні 100. Вибирали нітрат натрію як стандарт, оскільки він був 100-відсотковим водорозчинним, і це азотне добриво, яке зазвичай застосовується, коли концепція СІ вперше була запропонована в 1943 році. У добривах для вищого аналізу зазвичай нижчий рівень СІ, оскільки в ґрунтовому розчині міститься менше іонів солей на одиницю рослинних поживних речовин при їх розчиненні.

Зауважимо, що діюча речовина N (азот) і K (калій) звичайно використовуваних добрив мають більш високі значення СІ, ніж для діючої речовини Р (фосфор). SI змішаної рецептури, що містить N, P та / або K – це сума значень SI його компонентів. Хоча загальна SI для суміші NPK з високим аналізом може бути більшою, ніж для суміші NPK з низьким аналізом, SI в одиниці рослинних поживних речовин може бути нижчою у продукту з високим аналізом. Тому нижча норма добрив, необхідна для постачання такої ж кількості рослинних поживних речовин, піддає п насіння, що проростає меншим потенційно несприятливим впливам солі.

Слід зазначити, що СІ не передбачає точної кількості добрива чи складу добрив, які могли б призвести до пошкодження сільськогосподарських культур на певному ґрунті. Однак він порівнює один склад добрив з іншими щодо осмотичного (сольового) впливу. Він також показує, які добрива (ті, що мають більш високий рівень СІ), найімовірніше, спричинить травмування проростаючого насіння або саджанців, якщо їх розмістити близько до насіннєвого ряду (насіннєве ложе) або в ньому.

 

Salt content is one of the most critical characteristics of fertilizers that should be considered when fertilizers are applied, especially with seed-row or “in furrow” placement.

Summary: Salt index (SI) of a fertilizer is a measure of the salt concentration that fertilizer induces in the soil solution. SI does not predict the exact amount of a fertilizer material or formulation that could produce crop injury on a particular soil, but it does allow comparisons of fluid formulations regarding their potential salt effects. As we all know, placement of some formulations in or near the seed may decrease seed germination or result in seedling injury.

Fluid fertilizers containing potas­sium phosphate as the source of K have lower SI values than those containing KCI. When applied near the seed, fertilizers with lower SI values generally cause fewer prob­lems in seed germination or seedling injury. SI of any fluid formulation can be calculated using the SI values of the most common fertilizer sources. Dealers or growers then can select those formulations with lower SI values that best fit their needs.

Banding of nutrients has received much attention over the years. Usually, the fertilizer is placed at a depth greater than that of the seed to allow root interception of the fertilizer band as roots grow outward and downward in the soil.

Band vs. broadcast

Regions showing the greatest improvement in efficiency from banding over broadcasting lie in the northern U.S. and Canada, where colder soil conditions are experienced during spring seeding of row crops and small grains. Higher P rates are generally recommended if growers broadcast instead of band their fertilizers.

Banded P tends to be more efficient on very acid soils, highly calcareous soils, and those soils with very low levels of available soil P. Band applications also are usually more efficient when low P application rates are used.

Early planting dates, large amounts of crop residues on the soil surface, and soil compaction may subject plants to more stress. Banded nutrients are usually more effective for crops under these stress conditions. Vegetables respond well to banded fertilizers because they require a relatively large percentage of their total nutrients early in their growth period, and their rooting volume in the soil usually is restricted.

As extra equipment has been installed on planters over the years, it has become more difficult to have enough room to include the coulters required to open the soil for fertilizer placement below and to the side of the seed row. Some growers have quit applying starters because of this limitation and also because of the weight of openers for very large planters. Others have applied starters directly to the seed furrow, which does not require extra openers.

Other considerations.Banding away from the seed row is recommended over seed-row application under most conditions when applying higher nutrient rates, especially N, K, and S. Plants can efficiently use nutrients banded away from the seed row without adversely affecting seed germination or seedling emergence.

Recommendations for fertilizer place­ment in direct seed contact vary with crop. For many years maximum recom­mendations ranged from 10-20 lbs/A of N + K2O in direct seed contact with corn and sorghum. These applied to formula­tions using KCI as the K source and would not be accurate if potassium phosphate was used as the source of K instead of KCI. This is because of the lower SI value of potassium phosphate compared with KCI (Table 1).

Crop tolerance to increased osmotic pressures (salt content) of the soil solution in the vicinity of the seed varies considerably. For example, wheat is more tolerant of high salt conditions than is grain sorghum, while corn is intermediate. Tolerance of most oil-seed crops (soy­beans and cotton) to seed-row applica­tion of nutrients is very low, and seed ­row application of fertilizer for these crops should be viewed with caution.

Fluid fertilizers may produce a lower osmotic pressure in the soil solution than granular products of a similar grade. Fewer problems generally are encountered using fluids as seed-row fertilizers when com­pared to granular, since less soil water is required and salts are mainly dissolved in fluid formulations.

Seed-row application

This method refers to placement of relatively lower rates of nutrients in direct seed contact, usually for row crops. It also has been called “pop-up” or “in­ furrow” application, but “seed-row” is more descriptive. Seed-row placement increases the possibility of early root interception by nutrients.

Problems.Major concern of this practice is decreased seed germination or seedling injury caused by high salt concentrations in the soil solutions around germinating seeds.

Also, some starter components such as urea, UAN, or ammonium thiosulfate can produce free ammonia (NH3) under certain soil conditions. Direct seed contact by NH3 could result in poor germination or seedling death. Selection of the proper starter fertilizer is the way to minimize this occurrence.

Fertilizers best suited for seed-row application have 1) low salt index, 2) high water solubility, 3) contain N, P, K and S, with relatively high P content, 4) contain both urea and ammonium-nitrogen, 5) minimize content of compounds that liberate NH3, and 6) use potassium phosphate instead of KCl as the K source.

Salt index

Salt content is one of the most critical characteristics of fertilizers used for row-seed placement. The SI is a measure of the salt concentration that fertilizer induces in the soil solution.

The SI of a material is expressed as the ratio of the increase in osmotic pressure of the salt solution produced by a specific fertilizer to the osmotic pressure of the same weight of NaNO3, which is based on a relative value of 100. Sodium nitrate was chosen as the standard because it was 100 percent water soluble and it was a commonly used nitrogen fertilizer when the SI concept was first proposed in 1943. Higher analysis fertilizers usually have a lower SI because fewer ions of salts are placed in the soil solution per unit of plant nutrient when they dissolve.

Note that the N and K materials of commonly used fertilizers (Table 1) have higher SI values than those of P materi­als. The SI of a mixed formulation containing N, P, and/or K is the sum of the SI values of its components. Al­though the total SI for a high-analysis NPK mixture may be greater than that for a low-analysis NPK mixture, the SI per unit of plant nutrients may be lower in the high-analyses product. Therefore, the lower fertilizer rate needed to supply the same amount of plant nutrients subjects the germinating seeds to less potentially adverse salt effects.

It should be noted that the SI does not predict the exact amount of fertilizer material or a fertilizer formulation that could produce crop injury on a particular soil. However, it does compare one fertilizer formulation with others regarding the osmotic (salt) effects. It also shows which fertilizers (those with a higher SI) will be most likely to cause injury to germinating seeds or seedlings if placed close to or in the seed row.

Calculating salt index

The SI of a mixed fertilizer (NPKS) is the sum of the SI of each component per unit of plant nutrient times the number of units in that component. See Table 2 for SI calculations of 7-21­-7.

To calculate SI of any formulation:

  1. List the material, grade, and weight for each component in columns 1-3.
  2. Determine nutrient units in columns 4-6 by multiplying the weight of each component by its nutrient content and dividing each result by 20.
  3. List SI per plant nutrient unit in each component in column 7.
  4. Determine the SI due each compo­nent by multiplying the sum of the nutrient units in columns 4-6 times the corresponding SI value in column 7.
  5. Total individual SI values of all components in column 8.

SI values for a 6-24-6 formulation containing potassium phosphate are shown in Table 3. Phosphoric acid is first ammoniated to a 1-3-0 ratio, which results in an approximate 50-50 mixture of MAP and DAP at about pH 6.8. Potassium phosphate is then added to provide all of the K and remainder of the P Resulting SI of this grade and SI per unit of plant nutrients are much lower than those for 7-­21-7, which contained KCI.

Other points to consider are:

When K2SO4 is used instead of KCI, the SI is somewhat lower. However, the solubility of K2SO4 is lower than that of KCI, so this must be considered in producing formulations relatively high in K2O.

SI values of acids are given as values per 100 lbs of acid rather than a unit of 20 lbs. Also, the SI of H3P04 varies with P concentration of the acid.

SI values calculated differ for formula­tions when ammoniated phosphate solutions are prepared. SI per unit of N due to the ammoniating solution is not included because its contribution has already been accounted for in the SI per 100 lbs of H3PO4, since it has been converted to ammonium phosphate. The same method is used for calculating the SI of ammoniated H2S04 formulations.

SI values and SI per plant nutrient of some commonly used liquid formulations are listed in Table 4. Note that all formulations containing potassium phosphate have relatively low SI values. The two formulations containing KCI (7-­21-7 and 4-10-4) have much higher SI values and are not suggested for use in seed-row placement. These results show that SI of fluid fertilizers varies signifi­cantly, depending on the grade and components in the formulation.

Dr. Mortvedt, previously with the National Fertilizer and Environmental Research Center, TVA, Muscle Shoals, AL, and Colorado State University, is a consultant with U.S. Borax.

 

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